Preparation of Rearranged Allylic Isocyanates from the Reaction of Allylic Alcohols with 1-Cyano-4-dimethylaminopyridinium Bromide

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rearrangement.docx (155.64 KB)

Date

2018-10-11

Authors

Baidilov, Daler
Makarova, Mariia
Rycek, Lukas
Hudlicky, Tomas

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Volume Title

Publisher

Thieme

Abstract

A shorter and less costly alternative to Ichikawa’s [1,3]-transposition protocol for cyanates to isocyanates is described.

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Keywords

sigmatropic rearrangement, [1,3]-transposition, allylic alcohol, methodology, total synthesis

Citation

Synthesis 2018, 50, 4606–4610

URI

http://hdl.handle.net/10464/13885

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Chemistry

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